{"id":33023,"date":"2021-07-20T10:50:10","date_gmt":"2021-07-20T08:50:10","guid":{"rendered":"https:\/\/www.ub.edu\/in2ub\/?p=33023"},"modified":"2021-07-20T12:15:19","modified_gmt":"2021-07-20T10:15:19","slug":"double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo","status":"publish","type":"post","link":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/","title":{"rendered":"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO"},"content":{"rendered":"<p>Highlighted paper from <a href=\"https:\/\/www.ub.edu\/in2ub\/grup-de-recerca\/homogeneous-catalysis\/\" target=\"_blank\" rel=\"noopener\">Homogeneous Catalysis <\/a>group. The homochiral metal-organic framework TAMOF-1 was used as a heterogeneous catalyst in the kinetic resolution of styrene oxide by ring opening reactions with a set of anilines yielding secondary amino alcohols. The linear products arising from the attack on the non-benzylic position of styrene oxide underwent a second kinetic resolution by reacting with the epoxide, resulting in an amplification of its final enantiomeric excess and a concomitant formation of an array of isomeric aminodiols (substractive Horeau amplification effect). Computational studies rationalized the experimental results, providing a deep understanding of the whole process involving the two successive kinetic resolutions. These studies have revealed that TAMOF-1 lowered the reaction barriers of all ring opening processes taking place inside channels.<\/p>\n<p>Differentiation of Epoxide Enantiomers in the Confined Spaces of an Homochiral Cu(II) Metal-Organic Framework by Kinetic Resolution. <em>J. Cabezas-Gim\u00e9nez, V. Lillo, J.L. N\u00fa\u00f1ez-Rico, M.N. Corella-Ochoa, J. Jover, J.R. Gal\u00e1n-Mascar\u00f3s, A. Vidal-Ferran. <\/em><strong>Chemistry &#8211; A European Journal<\/strong>, June 2021. <a href=\"https:\/\/doi.org\/10.1002\/chem.202101367\" target=\"_blank\" rel=\"noopener\">https:\/\/doi.org\/10.1002\/chem.202101367<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Highlighted paper from Homogeneous Catalysis group. The homochiral metal-organic framework TAMOF-1 was used as a heterogeneous catalyst in the kinetic resolution of styrene oxide by ring opening reactions with a set of anilines yielding secondary amino alcohols. The linear products arising from the attack on the non-benzylic position of styrene oxide underwent a second kinetic&#8230;<\/p>\n","protected":false},"author":2,"featured_media":33013,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[19],"tags":[],"yoast_head":"<!-- This site is optimized with the Yoast SEO plugin v23.5 - https:\/\/yoast.com\/wordpress\/plugins\/seo\/ -->\n<title>Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB<\/title>\n<meta name=\"robots\" content=\"index, follow, max-snippet:-1, max-image-preview:large, max-video-preview:-1\" \/>\n<link rel=\"canonical\" href=\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/\" \/>\n<meta property=\"og:locale\" content=\"es_ES\" \/>\n<meta property=\"og:type\" content=\"article\" \/>\n<meta property=\"og:title\" content=\"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB\" \/>\n<meta property=\"og:description\" content=\"Highlighted paper from Homogeneous Catalysis group. The homochiral metal-organic framework TAMOF-1 was used as a heterogeneous catalyst in the kinetic resolution of styrene oxide by ring opening reactions with a set of anilines yielding secondary amino alcohols. The linear products arising from the attack on the non-benzylic position of styrene oxide underwent a second kinetic...\" \/>\n<meta property=\"og:url\" content=\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/\" \/>\n<meta property=\"og:site_name\" content=\"IN\u00b2UB\" \/>\n<meta property=\"article:published_time\" content=\"2021-07-20T08:50:10+00:00\" \/>\n<meta property=\"article:modified_time\" content=\"2021-07-20T10:15:19+00:00\" \/>\n<meta property=\"og:image\" content=\"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png\" \/>\n\t<meta property=\"og:image:width\" content=\"1280\" \/>\n\t<meta property=\"og:image:height\" content=\"720\" \/>\n\t<meta property=\"og:image:type\" content=\"image\/png\" \/>\n<meta name=\"author\" content=\"IN2UB\" \/>\n<meta name=\"twitter:card\" content=\"summary_large_image\" \/>\n<meta name=\"twitter:label1\" content=\"Escrito por\" \/>\n\t<meta name=\"twitter:data1\" content=\"IN2UB\" \/>\n\t<meta name=\"twitter:label2\" content=\"Tiempo de lectura\" \/>\n\t<meta name=\"twitter:data2\" content=\"1 minuto\" \/>\n<script type=\"application\/ld+json\" class=\"yoast-schema-graph\">{\"@context\":\"https:\/\/schema.org\",\"@graph\":[{\"@type\":\"WebPage\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/\",\"url\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/\",\"name\":\"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB\",\"isPartOf\":{\"@id\":\"https:\/\/www.ub.edu\/in2ub\/#website\"},\"primaryImageOfPage\":{\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage\"},\"image\":{\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage\"},\"thumbnailUrl\":\"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png\",\"datePublished\":\"2021-07-20T08:50:10+00:00\",\"dateModified\":\"2021-07-20T10:15:19+00:00\",\"author\":{\"@id\":\"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/fee647be08dbdfdd1486fbe8067be972\"},\"breadcrumb\":{\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#breadcrumb\"},\"inLanguage\":\"es\",\"potentialAction\":[{\"@type\":\"ReadAction\",\"target\":[\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/\"]}]},{\"@type\":\"ImageObject\",\"inLanguage\":\"es\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage\",\"url\":\"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png\",\"contentUrl\":\"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png\",\"width\":1280,\"height\":720},{\"@type\":\"BreadcrumbList\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#breadcrumb\",\"itemListElement\":[{\"@type\":\"ListItem\",\"position\":1,\"name\":\"Inici\",\"item\":\"https:\/\/www.ub.edu\/in2ub\/es\/\"},{\"@type\":\"ListItem\",\"position\":2,\"name\":\"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO\"}]},{\"@type\":\"WebSite\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/#website\",\"url\":\"https:\/\/www.ub.edu\/in2ub\/\",\"name\":\"IN\u00b2UB\",\"description\":\"Institut de Nanoci\u00e8ncia i Nanotecnologia - Universitat de Barcelona\",\"potentialAction\":[{\"@type\":\"SearchAction\",\"target\":{\"@type\":\"EntryPoint\",\"urlTemplate\":\"https:\/\/www.ub.edu\/in2ub\/?s={search_term_string}\"},\"query-input\":{\"@type\":\"PropertyValueSpecification\",\"valueRequired\":true,\"valueName\":\"search_term_string\"}}],\"inLanguage\":\"es\"},{\"@type\":\"Person\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/fee647be08dbdfdd1486fbe8067be972\",\"name\":\"IN2UB\",\"image\":{\"@type\":\"ImageObject\",\"inLanguage\":\"es\",\"@id\":\"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/image\/\",\"url\":\"https:\/\/secure.gravatar.com\/avatar\/15350879e1365c6016231f421f771d35?s=96&d=mm&r=g\",\"contentUrl\":\"https:\/\/secure.gravatar.com\/avatar\/15350879e1365c6016231f421f771d35?s=96&d=mm&r=g\",\"caption\":\"IN2UB\"},\"url\":\"https:\/\/www.ub.edu\/in2ub\/es\/author\/in2ub_doc\/\"}]}<\/script>\n<!-- \/ Yoast SEO plugin. -->","yoast_head_json":{"title":"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB","robots":{"index":"index","follow":"follow","max-snippet":"max-snippet:-1","max-image-preview":"max-image-preview:large","max-video-preview":"max-video-preview:-1"},"canonical":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/","og_locale":"es_ES","og_type":"article","og_title":"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB","og_description":"Highlighted paper from Homogeneous Catalysis group. The homochiral metal-organic framework TAMOF-1 was used as a heterogeneous catalyst in the kinetic resolution of styrene oxide by ring opening reactions with a set of anilines yielding secondary amino alcohols. The linear products arising from the attack on the non-benzylic position of styrene oxide underwent a second kinetic...","og_url":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/","og_site_name":"IN\u00b2UB","article_published_time":"2021-07-20T08:50:10+00:00","article_modified_time":"2021-07-20T10:15:19+00:00","og_image":[{"width":1280,"height":720,"url":"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png","type":"image\/png"}],"author":"IN2UB","twitter_card":"summary_large_image","twitter_misc":{"Escrito por":"IN2UB","Tiempo de lectura":"1 minuto"},"schema":{"@context":"https:\/\/schema.org","@graph":[{"@type":"WebPage","@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/","url":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/","name":"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO - IN\u00b2UB","isPartOf":{"@id":"https:\/\/www.ub.edu\/in2ub\/#website"},"primaryImageOfPage":{"@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage"},"image":{"@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage"},"thumbnailUrl":"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png","datePublished":"2021-07-20T08:50:10+00:00","dateModified":"2021-07-20T10:15:19+00:00","author":{"@id":"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/fee647be08dbdfdd1486fbe8067be972"},"breadcrumb":{"@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#breadcrumb"},"inLanguage":"es","potentialAction":[{"@type":"ReadAction","target":["https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/"]}]},{"@type":"ImageObject","inLanguage":"es","@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#primaryimage","url":"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png","contentUrl":"https:\/\/www.ub.edu\/in2ub\/wp-content\/uploads\/2021\/07\/Cataly_homog_2021.png","width":1280,"height":720},{"@type":"BreadcrumbList","@id":"https:\/\/www.ub.edu\/in2ub\/es\/double-catalytic-kinetic-resolution-via-substractive-horeau-amplification-in-the-confined-spaces-of-tamo\/#breadcrumb","itemListElement":[{"@type":"ListItem","position":1,"name":"Inici","item":"https:\/\/www.ub.edu\/in2ub\/es\/"},{"@type":"ListItem","position":2,"name":"Double Catalytic Kinetic Resolution via Substractive Horeau Amplification in the Confined Spaces of TAMO"}]},{"@type":"WebSite","@id":"https:\/\/www.ub.edu\/in2ub\/#website","url":"https:\/\/www.ub.edu\/in2ub\/","name":"IN\u00b2UB","description":"Institut de Nanoci\u00e8ncia i Nanotecnologia - Universitat de Barcelona","potentialAction":[{"@type":"SearchAction","target":{"@type":"EntryPoint","urlTemplate":"https:\/\/www.ub.edu\/in2ub\/?s={search_term_string}"},"query-input":{"@type":"PropertyValueSpecification","valueRequired":true,"valueName":"search_term_string"}}],"inLanguage":"es"},{"@type":"Person","@id":"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/fee647be08dbdfdd1486fbe8067be972","name":"IN2UB","image":{"@type":"ImageObject","inLanguage":"es","@id":"https:\/\/www.ub.edu\/in2ub\/#\/schema\/person\/image\/","url":"https:\/\/secure.gravatar.com\/avatar\/15350879e1365c6016231f421f771d35?s=96&d=mm&r=g","contentUrl":"https:\/\/secure.gravatar.com\/avatar\/15350879e1365c6016231f421f771d35?s=96&d=mm&r=g","caption":"IN2UB"},"url":"https:\/\/www.ub.edu\/in2ub\/es\/author\/in2ub_doc\/"}]}},"_links":{"self":[{"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/posts\/33023"}],"collection":[{"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/comments?post=33023"}],"version-history":[{"count":4,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/posts\/33023\/revisions"}],"predecessor-version":[{"id":33029,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/posts\/33023\/revisions\/33029"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/media\/33013"}],"wp:attachment":[{"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/media?parent=33023"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/categories?post=33023"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.ub.edu\/in2ub\/es\/wp-json\/wp\/v2\/tags?post=33023"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}